• • • Part of the book series (TOPCURRCHEM, volume 361) Abstract Literature published between 2008 and 2013 concerning the functionalization of carbon–hydrogen into carbon–phosphorus bonds is surveyed. The chapter is organized by reaction mechanism. The majority of methods still proceed via deprotonation of C–H into C–M (M=Li, Na, etc.) followed by reaction with a phosphorus electrophile P–X, where X is usually chlorine. A few examples of electrophilic aromatic substitution and related processes have also been reported, although this approach has not yet been developed significantly. Over the past 5 years a rapidly growing family of reactions includes transition metal “C–H activation” and formally related radical-based processes has been developed. The latter processes offer exciting prospects for the synthesis of organophosphorus compounds. Outliers Torrent Pdf.

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